Dishwashing detergent composition having a malodor control component and methods of cleaning dishware

ABSTRACT

A dishwashing detergent composition comprising a malodor control component, and methods of cleaning dishware are provided. In some embodiments, the dishwashing detergent composition comprises at least one volatile aldehyde and an acid catalyst.

FIELD OF THE INVENTION

The present invention relates to dishwashing detergent compositionshaving a malodor control component, and methods of cleaning dishware.

BACKGROUND OF THE INVENTION

Scented dishwashing detergent products for cleaning dishware are known.Typically, dishwashing detergent manufacturers develop perfumetechnology that provides a pleasant scent and masks malodors associatedwith soiled dishware.

However, not all odors are effectively controlled by products on themarket as amine-based malodors such as fish malodors, and sulfu'r-basedmalodors such as garlic and onion are difficult to combat. Further, thetime required for a product to noticeably combat malodors may createconsumer doubt as to a product's efficacy on malodors. For example, theconsumer may finish washing a dish and leave the area before the productbegins to noticeably reduce the malodor.

The difficulty in overcoming a broad range of malodors has spawned adiverse assortment of products to neutralize, mask, or contain themalodors. There remains a need for a dishwashing detergent compositionthat cleans dishware and is effective on a broad range of malodors,including amine-based and sulfur-based malodors, while not overpoweringmalodors with an overwhelming perfume.

SUMMARY OF THE INVENTION

In one embodiment, there is provided a dishwashing detergent compositioncomprising: (a) from about 0.1% to about 20% by weight of the totalcomposition of a chelant; (b) from about 5% to about 80% by weight ofthe total composition of a surfactant selected from the group consistingof anionic, nonionic, cationic, amphoteric, zwitterionic, semi-polarnonionic surfactants and mixtures thereof; and (c) a malodor controlcomponent comprising an effective amount of two or more volatilealdehydes for neutralizing a malodor, wherein said two or more volatilealdehydes are selected from the group consisting of 2-ethoxybenzylaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methyl furfural,5-methyl-thiophene-carboxaldehyde, adoxal, p-anisaldehyde,benzylaldehyde, bourgenal, cinnamic aldehyde, cymal, decyl aldehyde,floral super, florhydral, helional, lauric aldehyde, ligustral, lyral,melonal, o-anisaldehyde, pino acetaldehyde, P.T. bucinal, thiophenecarboxaldehyde, trans-4-decenal, trans trans 2,4-nonadienal, undecylaldehyde, and mixtures thereof.

In another embodiment, there is provided a dishwashing detergentcomposition comprising: (a) a chelant; (b) a surfactant selected fromthe group consisting of anionic, nonionic, cationic, amphoteric,zwitterionic, semi-polar nonionic surfactants, and mixtures thereof; and(c) a malodor control component comprising: (i) at least one volatilealdehyde; and (ii) an acid catalyst having a vapor pressure of about0.01 to about 13 at 25° C.; and (b) about 1% to about 5%, by weight ofsaid composition, of a low molecular weight monohydric alcohol.

In another embodiment, there is provided a method of cleaning a dishwarecomprising the steps of: applying a composition according to claim 1 onsaid dishware; and rinsing said composition off of said dishware.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a graph showing butanethiol reduction by thiophenecarboxaldehyde in combination with various acid catalysts.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to a dishwashing detergent compositionthat surprisingly provides excellent grease cleaning combined withsuperior shine and malodor control; and methods of cleaning dishware.

“Cleaning” means applying to a surface for the purpose of cleaning,and/or disinfecting.

“Dishware” means a surface such as dishes, glasses, pots, pans, bakingdishes and flatware made from ceramic, china, metal, glass, plastic(polyethylene, polypropylene, polystyrene, etc.) and wood.

“Dishwashing detergent composition” refers to those compositions thatare employed in manual (i.e. hand) dishwashing. Such compositions aregenerally high sudsing or foaming in nature.

“Grease” means materials comprising at least in part (i.e., at least 0.5wt % by weight of the grease) saturated and unsaturated fats and oils,alternatively oils and fats derived from animal sources such as beefand/or chicken.

“Malodor” refers to compounds generally offensive or unpleasant to mostpeople, such as the complex odors associated with bowel movements.

“Neutralize” or “neutralization” refers to the ability of a compound orproduct to reduce or eliminate malodorous compounds. Odor neutralizationmay be partial, affecting only some of the malodorous compounds in agiven context, or affecting only part of a malodorous compound. Amalodorous compound may be neutralized by chemical reaction resulting ina new chemical entity, by sequestration, by chelation, by association,or by any other interaction rendering the malodorous compound lessmalodorous or non-malodorous. Odor neutralization may be distinguishedfrom odor masking or odor blocking by a change in the malodorouscompound, as opposed to a change in the ability to perceive the malodorwithout any corresponding change in the condition of the malodorouscompound.

“Suds profile” means the amount of sudsing (high or low) and thepersistence of sudsing (sustained sudsing) throughout the washingprocess resulting from the use of the liquid detergent composition ofthe present composition. As used herein “high sudsing” refers to liquidhand dishwashing detergent compositions which are both high sudsing(i.e. a level of sudsing considered acceptable to the consumer) and havesustained sudsing (i.e. a high level of sudsing maintained throughoutthe dishwashing operation). This is particularly important with respectto liquid dishwashing detergent compositions as the consumer uses highsudsing as an indicator of the performance of the detergent composition.Moreover, the consumer of a liquid dishwashing detergent compositionalso uses the sudsing profile as an indicator that the wash solutionstill contains active detergent ingredients. The consumer usually renewsthe wash solution when the sudsing subsides. Thus, a low sudsing liquiddishwashing detergent composition formulation will tend to be replacedby the consumer more frequently than is necessary because of the lowsudsing level.

I. Dishwashing Detergent Composition

The dishwashing detergent composition generally contains from 30% to95%, alternatively 40% to 80%, alternatively 50% to 75% of an aqueousliquid carrier, in which the other essential and optional compositionscomponents are dissolved, dispersed or suspended.

A. Chelant

The composition of the present invention comprises a chelant at a levelof from 0.1% to 20%, alternatively from 0.2% to 5%, alternatively from0.2% to 3% by weight of total composition.

As commonly understood in the detergent field, chelation herein meansthe binding or complexation of a bi- or multidentate ligand. Theseligands, which are often organic compounds, are called chelants,chelators, chelating agents, and/or sequestering agent. Chelating agentsform multiple bonds with a single metal ion. Chelants, are chemicalsthat form soluble, complex molecules with certain metal ions,inactivating the ions so that they cannot normally react with otherelements or ions to produce precipitates or scale. The ligand forms achelate complex with the substrate. The term is reserved for complexesin which the metal ion is bound to two or more atoms of the chelant. Thechelants for use in the present invention are those having crystalgrowth inhibition properties, i.e. those that interact with the smallcalcium and magnesium carbonate particles preventing them fromaggregating into hard scale deposit. The particles repel each other andremain suspended in the water or form loose aggregates which may settle.These loose aggregates are easily rinsed away and do not form a deposit.

Suitable chelating agents can be selected from the group consisting ofamino carboxylates, amino phosphonates, polufanctionally-substitutedaromatic chelating agents and mixtures thereof.

Suitable chelants for use herein are also the amino acids basedchelants, alternatively glutamic-N,N-diacetic acid and derivativesand/or phosphonate based chelants, alternatively diethylenetriaminepenta methylphosphonic acid.

Amino carboxylates include ethylenediaminetetra-acetates,N-hydroxyethylethylenediaminetriacetates, nitrilo-triacetates,ethylenediamine tetrapro-prionates, triethylenetetraaminehexacetates,diethylenetriaminepentaacetates, and ethanoldi-glycines, alkali metal,ammonium, and substituted ammonium salts therein and mixtures therein.As well as MGDA (methyl-glycine-diacetic acid), and salts andderivatives thereof and GLDA (glutamic-N,N-diacetic acid) and salts andderivatives thereof. In one embodiment, the composition comprises GLDA(salts and derivatives thereof). In another embodiment, the compositioncomprises tetrasodium salt.

Other suitable chelants include amino acid based compound or a succinatebased compound. The term “succinate based compound” and “succinic acidbased compound” are used interchangeably herein. Other suitable chelantsare described in U.S. Pat. No. 6,426,229. Particular suitable chelantsinclude; for example, aspartic acid-N-monoacetic acid (ASMA), asparticacid-N,N-diacetic acid (ASDA), aspartic acid-N-monopropionic acid(ASMP), iminodisuccinic acid (IDS), Imino diacetic acid (IDA),N-(2-sulfomethyl) aspartic acid (SMAS), N-(2-sulfoethyl) aspartic acid(SEAS), N-(2-sulfomethyl) glutamic acid (SMGL), N-(2-sulfoethyl)glutamic acid (SEGL), N-methyliminodiacetic acid (MIDA),-alanine-N,N-diacetic acid (-ALDA), serine-N,N-diacetic acid (SEDA),isoserine-N,N-diacetic acid (ISDA), phenylalanine-N,N-diacetic acid(PHDA), anthranilic acid-N,N-diacetic acid (ANDA), sulfanilicacid-N,N-diacetic acid (SLDA), taurine-N,N-diacetic acid (TUDA) andsulfomethyl-N,N-diacetic acid (SMDA) and alkali metal salts or ammoniumsalts thereof. Also suitable is ethylenediamine disuccinate (“EDDS”),especially the [S,S] isomer as described in U.S. Pat. No. 4,704,233.Furthermore, Hydroxyethyleneiminodiacetic acid, Hydroxyiminodisuccinicacid, Hydroxyethylene diaminetriacetic acid are also suitable.

Other chelants include homopolymers and copolymers of polycarboxylicacids and their partially or completely neutralized salts, monomericpolycarboxylic acids and hydroxycarboxylic acids and their salts.Suitable salts of the abovementioned compounds are the ammonium and/oralkali metal salts, i.e. the lithium, sodium, and potassium salts.

Suitable polycarboxylic acids are acyclic, alicyclic, heterocyclic andaromatic carboxylic acids, in which case they contain at least twocarboxyl groups which are in each case separated from one another by,alternatively, no more than two carbon atoms. Polycarboxylates whichcomprise two carboxyl groups include, for example, water-soluble saltsof, malonic acid, (ethyl enedioxy) diacetic acid, maleic acid,diglycolic acid, tartaric acid, tartronic acid and fumaric acid.

Polycarboxylates which contain three carboxyl groups include, forexample, water-soluble citrate. Correspondingly, a suitablehydroxycarboxylic acid is, for example, citric acid. Another suitablepolycarboxylic acid is the homopolymer of acrylic acid. In oneembodiment, the composition includes the polycarboxylates end cappedwith sulfonates.

Amino phosphonates are also suitable for use as chelating agents andinclude ethylenediaminetetrakis (methylenephosphonates) as DEQUEST. Inone embodiment, the composition includes amino phosphonates that do notcontain alkyl or alkenyl groups with more than about 6 carbon atoms.

Polyfunctionally-substituted aromatic chelating agents are also usefulin the compositions herein such as described in U.S. Pat. No. 3,812,044.In one embodiment, the composition includes dihydroxydisulfobenzenessuch as 1,2-dihydroxy-3,5-disulfobenzene.

Further suitable polycarboxylates chelants for use herein include citricacid, lactic acid, acetic acid, succinic acid, formic acid; allalternatively in the form of a water-soluble salt. Other suitablepolycarboxylates are oxodisuccinates, carboxymethyloxysuccinate andmixtures of tartrate monosuccinic and tartrate disuccinic acid such asdescribed in U.S. Pat. No. 4,663,071.

B. Surfactants

The composition of the present invention may comprise a surfactantselected from anionic, nonionic, cationic, amphoteric, zwitterionic,semi-polar nonionic surfactants, and mixtures thereof. The surfactantsof the composition will have an average branching of the alkyl chain(s)of more than 10%, alternatively more than 20%, alternatively more than30%, alternatively more than 40%, by weight of the total surfactants.

The surfactants of the present invention will generally be present at alevel of 5% to 80%, alternatively 10% to 60%, alternatively 12% to 45%,by weight of the total composition.

In one embodiment, the composition of the present invention will furthercomprise a nonionic surfactant at a weight ratio of total surfactant tononionic surfactant of 2 to 10, alternatively of 2 to 7.5, alternativelyof 2 to 6.

The surfactants described below can be used in their linear and/orbranched version.

1. Nonionic Surfactants

It has been found that the addition of nonionic surfactants,alternatively of branched nonionic surfactants, will prevent efficientlythe formation of crystalline films of the dish surface and will provideimproved wetting and thereby providing superior shine.

Nonionic surfactants are present in a typical amount of from 2% to 40%,alternatively 3% to 30% by weight of the liquid detergent compositionand alternatively from 3 to 20% by weight of the total composition.Suitable nonionic surfactants include the condensation products ofaliphatic alcohols with from 1 to 25 moles of ethylene oxide. The alkylchain of the aliphatic alcohol can either be straight or branched,primary or secondary, and generally contains from 8 to 22 carbon atoms.In one embodiment, the composition includes the condensation products ofalcohols having an alkyl group containing from 8 to 18 carbon atoms,alternatively from 9 to 15 carbon atoms with from 2 to 18 moles,alternatively 2 to 15, alternatively 5-12 of ethylene oxide per mole ofalcohol.

Also suitable are alkylpolyglycosides having the formulaR²O(C_(n)H_(2n)O)_(t)(glycosyl)_(x) (formula (III)), wherein R² offormula (III) is selected from the group consisting of alkyl,alkyl-phenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof inwhich the alkyl groups contain from 10 to 18, alternatively from 12 to14, carbon atoms; n of formula (III) is 2 or 3, alternatively 2; t offormula (III) is from 0 to 10, alternatively 0; and x of formula (III)is from 1.3 to 10, alternatively from 1.3 to 3, most alternatively from1.3 to 2.7. The glycosyl is alternatively derived from glucose. Alsosuitable are alkyl glycerol ethers and sorbitan esters.

Also suitable are fatty acid amide surfactants having the formula (IV):

wherein R⁶ of formula (IV) is an alkyl group containing from 7 to 21,alternatively from 9 to 17, carbon atoms and each R⁷ of formula (IV) isselected from the group consisting of hydrogen, C₁-C₄ alkyl, C₁-C₄hydroxyalkyl, and —(C₂H₄O)_(x)H where x of formula (IV) varies from 1 to3. Suitable amides are C₈-C₂₀ ammonia amides, monoethanolamides,diethanolamides, and isopropanolamides.

Suitable nonionic surfactants for use in the present invention are thecondensation products of aliphatic alcohols with ethylene oxide, such asthe mixture of nonyl (C9), decyl (C10) undecyl (C11) alcohol modifiedwith on average 5 ethylene oxide (EO) units such as the commerciallyavailable Neodol 91-5 or the Neodol 91-8 that is modified with onaverage 8 EO units. Also suitable are the longer alkyl chainsethoxylated nonionics such as C12, C13 modified with 5 EO (Neodol 23-5).Neodol is a Shell tradename. Also suitable is the C12, C14 alkyl chainwith 7 EO, commercially available under the trade name Novel 1412-7(Sasol) or the Lutensol A 7 N (BASF)

Suitable branched nonionic are the Guerbet C10 alcohol ethoxylates with5 EO such as Ethylan 1005, Lutensol XP 50 and the Guerbet C10 alcoholalkoxylated nonionics (modified with EO and PO=propyleneoxyde) such asthe commercially available Lutensol XL series (X150, XL70, . . . ).Other branching also include oxo branched nonionic surfactants such asthe Lutensol ON 50 (5 EO) and Lutensol ON70 (7 EO). Other suitablebranched nonionics are the ones derived from the isotridecyl alcohol andmodified with ethyleneoxyde such as the Lutensol TO7 (7EO) from BASF andthe Marlipal O 13/70 (7EO) from Sasol. Also suitable are the ethoxylatedfatty alcohols originating from the Fisher & Troshp reaction comprisingup to 50% branching (40% methyl (mono or bi) 10% cyclohexyl) such asthose produced from the Safol™ alcohols from Sasol; ethoxylated fattyalcohols originating from the oxo reaction wherein at least 50 weight %of the alcohol is C2 isomer (methyl to pentyl) such as those producedfrom the Isalchem™ alcohols or Lial™ alcohols from Sasol; theethoxylated fatty alcohols originating from the modified oxo reactionwherein at least 15 weight % of the alcohol is C2 isomer (methyl topentyl) such as those produced from the Neodol™ alcohols from Shell

2. Amphoteric/Zwitterionic Surfactants

The amphoteric and zwitterionic surfactanta can be present at a level offrom 0.01% to 20%, alternatively from 0.2% to 15%, alternatively 0.5% to10%, by weight of the composition. The compositions of the presentinvention may further comprise an amine oxide and/or a betaine.

In one embodiment, the composition includes amine oxides are cocodimethyl amine oxide or coco amido propyl dimethyl amine oxide. Amineoxide may have a linear or mid-branched alkyl moiety. Typical linearamine oxides include water-soluble amine oxides containing one R1 C₈₋₁₈alkyl moiety and 2 R2 and R3 moieties selected from the group consistingof C₁₋₃ alkyl groups and C₁₋₃ hydroxyalkyl groups. Alternatively, amineoxide is characterized by the formula R1-N(R2)(R3)→O wherein R₁ is aC₈₋₁₈ alkyl and R₂ and R₃ are selected from the group consisting ofmethyl, ethyl, propyl, isopropyl, 2-hydroxethyl, 2-hydroxypropyl and3-hydroxypropyl. The linear amine oxide surfactants in particular mayinclude linear C₁₀-C₁₈ alkyl dimethyl amine oxides and linear C₈-C₁₂alkoxy ethyl dihydroxy ethyl amine oxides. Suitable amine oxides includelinear C₁₀, linear C₁₀-C₁₂, and linear C₁₂-C₁₄ alkyl dimethyl amineoxides.

As used herein “mid-branched” means that the amine oxide has one alkylmoiety having n₁ carbon atoms with one alkyl branch on the alkyl moietyhaving n₂ carbon atoms. The alkyl branch is located on the α carbon fromthe nitrogen on the alkyl moiety. This type of branching for the amineoxide is also known in the art as an internal amine oxide. The total sumof n₁ and n₂ is from 10 to 24 carbon atoms, alternatively from 12 to 20,and alternatively from 10 to 16. The number of carbon atoms for the onealkyl moiety (n₁) should be approximately the same number of carbonatoms as the one alkyl branch (n₂) such that the one alkyl moiety andthe one alkyl branch are symmetric. As used herein “symmetric” meansthat |n₁−n₂| is less than or equal to 5, alternatively 4, alternativelyfrom 0 to 4 carbon atoms in at least 50 wt %, alternatively at least 75wt % to 100 wt % of the mid-branched amine oxides for use herein.

The amine oxide further comprises two moieties, independently selectedfrom a C₁₋₃ alkyl, a C₁₋₃ hydroxyalkyl group, or a polyethylene oxidegroup containing an average of from about 1 to about 3 ethylene oxidegroups. Alternatively, the two moieties are selected from a C₁₋₃ alkyl,alternatively both are selected as a C₁ alkyl.

Other suitable surfactants include betaines such alkyl betaines,alkylamidobetaine, amidazoliniumbetaine, sulfobetaine (INCI Sultaines)as well as the Phosphobetaine and alternatively meets formula I:

R¹-[CO—X (CH₂)_(n)]_(x)—N⁺(R²)(R₃)—(CH₂)_(m)—[H(OH)—CH₂]_(y)—Y—  (I)wherein

-   -   R¹ is a saturated or unsaturated C₆₋₂₂ alkyl residue,        alternatively C₈₋₁₈ alkyl residue, in particular a saturated        C10-16 alkyl residue, for example a saturated C12-14 alkyl        residue;    -   X is NH, NR⁴ with C₁₋₄ Alkyl residue R⁴, O or S,    -   n a number from 1 to 10, alternatively 2 to 5, in particular 3,    -   x 0 or 1, alternatively 1,    -   R², R³ are independently a C₁₋₄ alkyl residue, potentially        hydroxy substituted such as a hydroxyethyl, alternatively a        methyl.    -   m a number from 1 to 4, in particular 1, 2 or 3,    -   y 0 or 1 and    -   Y is COO, SO3, OPO(OR⁵)O or P(O)(OR⁵)O, whereby R⁵ is a hydrogen        atom H or a C1-4 alkyl residue.

Suitable betaines are the alkyl betaines of the formula (Ia), the alkylamido betaine of the formula (Ib), the Sulfo betaines of the formula(Ic) and the Amido sulfobetaine of the formula (Id);

R¹—N⁺(CH₃)₂—CH₂COO⁻  (Ia)

R¹—CO—NH(CH₂)₃—N⁺(CH₃)₂—CH₂COO⁻  (Ib)

R¹—N⁺(CH₃)₂—CH₂CH(OH)CH₂SO₃—  (Ic)

R¹—CO—NH—(CH₂)₃—N⁺(CH₃)₂—CH₂CH(OH)CH₂SO₃—  (Id)

in which R¹¹ as the same meaning as in formula I. Suitable betaines arethe Carbobetaine[wherein Y⁻═COO⁻], in particular the Carbobetaine of the formula (Ia)and (Ib), alternatively the Alkylamidobetaine of the formula (Ib).]

Examples of suitable betaines and sulfobetaine are the following[designated in accordance with INCI]: Almondamidopropyl of betaines,Apricotam idopropyl betaines, Avocadamidopropyl of betaines,Babassuamidopropyl of betaines, Behenam idopropyl betaines, Behenyl ofbetaines, betaines, Canolam idopropyl betaines, Capryl/Capram idopropylbetaines, Carnitine, Cetyl of betaines, Cocamidoethyl of betaines, Cocamidopropyl betaines, Cocam idopropyl Hydroxysultaine, Coco betaines, CocoHydroxysultaine, Coco/Oleam idopropyl betaines, Coco Sultaine, Decyl ofbetaines, Dihydroxyethyl Oleyl Glycinate, Dihydroxyethyl Soy Glycinate,Dihydroxyethyl Stearyl Glycinate, Dihydroxyethyl Tallow Glycinate,Dimethicone Propyl of PG-betaines, Erucam idopropyl Hydroxysultaine,Hydrogenated Tallow of betaines, Isostearam idopropyl betaines, Lauramidopropyl betaines, Lauryl of betaines, Lauryl Hydroxysultaine, LaurylSultaine, Milkam idopropyl betaines, Minkamidopropyl of betaines,Myristam idopropyl betaines, Myristyl of betaines, Oleam idopropylbetaines, Oleam idopropyl Hydroxysultaine, Oleyl of betaines,Olivamidopropyl of betaines, Palmam idopropyl betaines, Palm itamidopropyl betaines, Palmitoyl Carnitine, Palm Kernelam idopropylbetaines, Polytetrafluoroethylene Acetoxypropyl of betaines, Ricinoleamidopropyl betaines, Sesam idopropyl betaines, Soyam idopropyl betaines,Stearam idopropyl betaines, Stearyl of betaines, Tallowam idopropylbetaines, Tallowam idopropyl Hydroxysultaine, Tallow of betaines, TallowDihydroxyethyl of betaines, Undecylenam idopropyl betaines and WheatGermam idopropyl betaines. In one embodiment, the composition includesCocam idopropyl betaines (Cocoamidopropylbetain).

3. Anionic Surfactants

Suitable anionic surfactants to be used in the compositions and methodsof the present invention are sulfates, sulfosuccinates, sulfoacetates,and/or sulfonates; alternatively alkyl sulfate and/or alkyl ethoxysulfates; alternatively a combination of alkyl sulfates and/or alkylethoxy sulfates with a combined ethoxylation degree less than 5,alternatively less than 3, alternatively less than 2.

Sulphate or sulphonate surfactant is typically present at a level of atleast 5%, alternatively from 5% to 40%, alternatively from 15% to 30%,alternatively at 15% to 25%, by weight of the liquid detergentcomposition.

Suitable sulphate or sulphonate surfactants for use in the compositionsherein include water-soluble salts or acids of C₁₀-C₁₄ alkyl orhydroxyalkyl, sulphate or sulphonates. Suitable counterions includehydrogen, alkali metal cation or ammonium or substituted ammonium, butalternatively sodium. Where the hydrocarbyl chain is branched, italternatively comprises C₁₋₄ alkyl branching units. The averagepercentage branching of the sulphate or sulphonate surfactant isalternatively greater than 30%, alternatively from 35% to 80%,alternatively from 40% to 60% of the total hydrocarbyl chains.

The sulphate or sulphonate surfactants may be selected from C₁₁-C₁₈alkyl benzene sulphonates (LAS), C₈-C₂₀ primary, branched-chain andrandom alkyl sulphates (AS); C₁₀-C₁₈ secondary (2,3) alkyl sulphates;C₁₀-C₁₈ alkyl alkoxy sulphates (AE_(x)S) wherein alternatively x is from1-30; C₁₀-C₁₈ alkyl alkoxy carboxylates alternatively comprising 1-5ethoxy units; mid-chain branched alkyl sulphates as discussed in U.S.Pat. No. 6,020,303 and U.S. Pat. No. 6,060,443; mid-chain branched alkylalkoxy sulphates as discussed in U.S. Pat. No. 6,008,181 and U.S. Pat.No. 6,020,303; modified alkylbenzene sulphonate (MLAS) as discussed inWO 99/05243, WO 99/05242, WO 99/05244, WO 99/05082, WO 99/05084, WO99/05241, WO 99/07656, WO 00/23549, and WO 00/23548; methyl estersulphonate (MES); and alpha-olefin sulphonate (AOS).

The paraffin sulphonates may be monosulphonates or disulphonates andusually are mixtures thereof, obtained by sulphonating paraffins of 10to 20 carbon atoms. Suitable sulphonates are those of C12-18 carbonatoms chains and alternatively they are C14-17 chains. Paraffinsulphonates that have the sulphonate group(s) distributed along theparaffin chain are described in U.S. Pat. No. 2,503,280; U.S. Pat. No.2,507,088; U.S. Pat. No. 3,260,744; U.S. Pat. No. 3,372.188 and in DE735 096.

Also suitable are the alkyl glyceryl sulphonate surfactants and/or alkylglyceryl sulphate surfactants described in WO06/014740: A mixture ofoligomeric alkyl glyceryl sulfonate and/or sulfate surfactant selectedfrom dimers, trimers, tetramers, pentamers, hexamers, heptamers, andmixtures thereof; wherein the weight percentage of monomers is from 0 wt% to 60 wt % by weight of the alkyl glyceryl sulfonate and/or sulfatesurfactant mixture.

Other suitable anionic surfactants are alkyl, alternatively dialkylsulfosuccinates and/or sulfoacetate. The dialkyl sulfosuccinates may bea C₆₋₁₅ linear or branched dialkyl sulfosuccinate. The alkyl moietiesmay be symmetrical (i.e., the same alkyl moieties) or asymmetrical(i.e., different alkyl moiety.es). Alternatively, the alkyl moiety issymmetrical.

Most common branched anionic alkyl ether sulphates are obtained viasulfation of a mixture of the branched alcohols and the branched alcoholethoxylates. Also suitable are the sulfated fatty alcohols originatingfrom the Fisher & Troshp reaction comprising up to 50% branching (40%methyl (mono or bi) 10% cyclohexyl) such as those produced from theSafol™ alcohols from Sasol; sulfated fatty alcohols originating from theoxo reaction wherein at least 50 weight % of the alcohol is C2 isomer(methyl to pentyl) such as those produced from the Isalchem™ alcohols orLial™ alcohols from Sasol; the sulfated fatty alcohols originating fromthe modified oxo reaction wherein at least 15 weight % of the alcohol isC2 isomer (methyl to pentyl) such as those produced from the Neodol™alcohols from Shell.

4. Cationic Surfactants

Cationic surfactants, when present in the composition, are present in aneffective amount, alternatively from 0.1% to 20%, by weight of thecomposition. Suitable cationic surfactants are quaternary ammoniumsurfactants. Suitable quaternary ammonium surfactants are selected fromthe group consisting of mono C₆-C₁₆, alternatively C₆-C₁₀ N-alkyl oralkenyl ammonium surfactants, wherein the remaining N positions aresubstituted by methyl, hydroxyehthyl or hydroxypropyl groups. Anothersuitable cationic surfactant is an C₆-C₁₈ alkyl or alkenyl ester of aquaternary ammonium alcohol, such as quaternary chlorine esters.Alternatively, the cationic surfactants have the formula (V):

wherein R1 of formula (V) is C₈-C₁₈ hydrocarbyl and mixtures thereof,alternatively, C₈₋₁₄ alkyl, alternatively, C₈, C₁₀ or C₁₂ alkyl, and Xof formula (V) is an anion, alternatively, chloride or bromide.

C. Cleaning Polymer

The composition of the present invention can further comprise one ormore alkoxylated polyethyleneimine polymer. The composition may comprisefrom 0.01 wt % to 10 wt %, alternatively from 0.01 wt % to 2 wt %,alternatively from 0.1 wt % to 1.5 wt %, alternatively from 0.2% to1.5%, by weight of the composition, of an alkoxylated polyethyleneiminepolymer as described on page 2, line 33 to page 5, line 5 andexemplified in examples 1 to 4 at pages 5 to 7 of WO2007/135645.

The alkoxylated polyethyleneimine polymer of the present composition hasa polyethyleneimine backbone having from 400 to 10000 weight averagemolecular weight, alternatively from 400 to 7000 weight averagemolecular weight, alternatively from 3000 to 7000 weight averagemolecular weight.

These polyamines can be prepared for example, by polymerizingethyleneimine in presence of a catalyst such as carbon dioxide, sodiumbisulfite, sulfuric acid, hydrogen peroxide, hydrochloric acid, aceticacid, and the like.

The alkoxylation of the polyethyleneimine backbone includes: (1) one ortwo alkoxylation modifications per nitrogen atom, dependent on whetherthe modification occurs at a internal nitrogen atom or at an terminalnitrogen atom, in the polyethyleneimine backbone, the alkoxylationmodification consisting of the replacement of a hydrogen atom on apolyalkoxylene chain having an average of about 1 to about 40 alkoxymoieties per modification, wherein the terminal alkoxy moiety of thealkoxylation modification is capped with hydrogen, a C₁-C₄ alkyl ormixtures thereof; (2) a substitution of one C₁-C₄ alkyl moiety or benzylmoiety and one or two alkoxylation modifications per nitrogen atom,dependent on whether the substitution occurs at a internal nitrogen atomor at an terminal nitrogen atom, in the polyethyleneimine backbone, thealkoxylation modification consisting of the replacement of a hydrogenatom by a polyalkoxylene chain having an average of about 1 to about 40alkoxy moieties per modification wherein the terminal alkoxy moiety iscapped with hydrogen, a C₁-C₄ alkyl or mixtures thereof; or (3) acombination thereof.

The composition may further comprise the amphiphilic graft polymersbased on water soluble polyalkylene oxides (A) as a graft base and sideschains formed by polymerization of a vinyl ester component (B), saidpolymers having an average of ≦1 graft site per 50 alkylene oxide unitsand mean molar mass Mw of from 3,000 to 100,000 described in BASF patentapplication WO2007/138053 on pages 2 line 14 to page 10, line 34 andexemplified on pages 15-18.

D. Salts and Solvents

Salts and solvents are generally used to ensure preferred productquality for dissolution, thickness and aesthetics and to ensure betterprocessing. When salts are included, the ions can be selected frommagnesium, sodium, potassium, calcium, and/or magnesium andalternatively from sodium and magnesium, and are added as a hydroxide,chloride, acetate, sulphate, formate, oxide or nitrate salt to thecompositions of the present invention. Salts are generally present at anactive level of from 0.01% to 5%, alternatively from 0.015% to 3%,alternatively from 0.025% to 2.0%, by weight of the liquid detergentcomposition. In one embodiment, additional magnesium ions may beavoided.

Suitable solvents include C1-C5 alcohols are according to the formulaR—OH wherein R is a linear saturated alkyl group of from 1 to 5 carbonatoms, alternatively from 2 to 4. Suitable alcohols are ethanol,propanol, isopropanol or mixtures thereof. Other suitable alcohols arealkoxylated C1-8 alcohols according to the formula R (A0n-oh wherein Ris a linear alkyl group of from 1 to 8 carbon atoms, alternatively from3 to 6, wherein A is an alkoxy group alternatively propoxy and/or ethoxyand n is an integer of from 1 to 5, alternatively from 1 to 2. Suitablealcohols are buthoxy propoxy propanol (n-BPP), buthoxy Propanol (n-BP)buthoxyethanol or mixtures thereof. Suitable alkoxylated aromaticalcohols to be used herein are according to the formula R (B)n-OHwhereinm R is an alkyl substituted or non alkyl substituted aryl groupof from 1 to 20 carbon atoms, alternatively from 2 to 15 andalternatively from 2 to 10, wherein B is an alkoxy group alternativelybuthoxy, propoxy and/or ethoxy and n is an integer from of from 1 to 5,alternatively from 1 to 2. Suitable alkoxylated aromatic alcohols arebenzoyethanol and or benzoypropanol. A suitable aromatic alcohol to beused herein is benzyl alcohol. Other suitable solvents include butyldiglycolether, benzylalcohol, propoxyporpoxypropanol (EP 0 859 044)ethers and diethers, glycols, alkoxylated glycols, C₆-C₁₆ glycol ethers,alkoxylated aromatic alcohols, aromatic alcohols, aliphatic branchedalcohols, alkoxylated aliphatic branched alcohols, alkoxylated linearC₁-C₅ alcohols, linear C₁-C₅ alcohols, amines, C₈-C₁₄ alkyl andcycloalkyl hydrocarbons and halohydrocarbons, and mixtures thereof.

When present, the liquid detergent composition may contain from 0.01% to20%, alternatively from 0.5% to 20%, alternatively from 1% to 10%, byweight of the composition, of a solvent. These solvents may be used inconjunction with an aqueous liquid carrier, such as water, or they maybe used without any aqueous liquid carrier being present.

E. Hydrotrope

The dishwashing detergent compositions of the present invention mayoptionally comprise a hydrotrope in an effective amount so that theliquid detergent compositions are appropriately compatible in water.Suitable hydrotropes for use herein include anionic-type hydrotropes,particularly sodium, potassium, and ammonium xylene sulphonate, sodium,potassium and ammonium toluene sulphonate, sodium potassium and ammoniumcumene sulphonate, and mixtures thereof, and related compounds, asdisclosed in U.S. Pat. No. 3,915,903.

The compositions of the present invention typically comprise from 0% to15% by weight of the liquid detergent composition of a hydrotropic, ormixtures thereof, alternatively from 1% to 10%, most alternatively from3% to 6% by weight.

F. Polymeric Suds Stabilizer

The compositions of the present invention may optionally contain apolymeric suds stabilizer. These polymeric suds stabilizers provideextended suds volume and suds duration of the liquid detergentcompositions. These polymeric suds stabilizers may be selected fromhomopolymers of (N,N-dialkylamino) alkyl esters and (N,N-dialkylamino)alkyl acrylate esters. The weight average molecular weight of thepolymeric suds boosters, determined via conventional gel permeationchromatography, is from 1,000 to 2,000,000, alternatively from 5,000 to1,000,000, alternatively from 10,000 to 750,000, alternatively from20,000 to 500,000, even alternatively from 35,000 to 200,000. Thepolymeric suds stabilizer can optionally be present in the form of asalt, either an inorganic or organic salt, for example the citrate,sulphate, or nitrate salt of (N,N-dimethylamino)alkyl acrylate ester.

In one embodiment, the composition includes a suds stabilizer that is(N,N-dimethylamino)alkyl acrylate esters, namely the acrylate esterrepresented by the formula (VII):

Other suitable suds boosting polymers are copolymers ofhydroxypropylacrylate/dimethyl aminoethylmethacrylate (copolymer ofHPA/DMAM), represented by the formulae VIII and IX

When present in the compositions, the polymeric suds booster/stabilizermay be present in the composition from 0.01% to 15%, alternatively from0.05% to 10%, alternatively from 0.1% to 5%, by weight of thecomposition.

Another suitable class of polymeric suds booster polymers arehydrophobically modified cellulosic polymers having a number averagemolecular weight (Mw) below 45,000; alternatively between 10,000 and40,000; alternatively between 13,000 and 25,000. The hydrophobicallymodified cellulosic polymers include water soluble cellulose etherderivatives, such as nonionic and cationic cellulose derivatives. In oneembodiment, the composition includes methylcellulose, hydroxypropylmethylcellulose, hydroxyethyl methylcellulose, or mixtures thereof.

G. Diamines

Another optional ingredient in the composition of the present inventionis a diamine. Since the habits and practices of the users of liquiddetergent compositions show considerable variation, the composition willalternatively contain 0% to 15%, alternatively 0.1% to 15%,alternatively 0.2% to 10%, alternatively 0.25% to 6%, alternatively 0.5%to 1.5% by weight of said composition, of at least one diamine.

Suitable organic diamines are those in which pK1 and pK2 are in therange of 8.0 to 11.5, alternatively in the range of 8.4 to 11, evenalternatively from 8.6 to 10.75. Suitable materials include1,3-bis(methylamine)-cyclohexane (pKa=10 to 10.5), 1,3 propane diamine(pK1=10.5; pK2=8.8), 1,6 hexane diamine (pK1=11; pK2=10), 1,3 pentanediamine (DYTEK EP®) (pK1=10.5; pK2=8.9), 2-methyl 1,5 pentane diamine(DYTEK AC)) (pK1=11.2; pK2=10.0). Other suitable materials includeprimary/primary diamines with alkylene spacers ranging from C₄ to C₈. Ingeneral, it is believed that primary diamines are preferred oversecondary and tertiary diamines. pKa is used herein in the same manneras is commonly known to people skilled in the art of chemistry: in anall-aqueous solution at 25° C. and for an ionic strength between 0.1 to0.5 M. Values referenced herein can be obtained from literature, such asfrom “Critical Stability Constants: Volume 2, Amines” by Smith andMartel, Plenum Press, NY and London, 1975.

H. Carboxylic Acid

The dishwashing detergent compositions of the present invention maycomprise a linear or cyclic carboxylic acid or salt thereof to improvethe rinse feel of the composition. The presence of anionic surfactants,especially when present in higher amounts in the region of 15-35% byweight of the composition, results in the composition imparting aslippery feel to the hands of the user and the dishware.

Carboxylic acids useful herein include C₁₋₆ linear or at least 3 carboncontaining cyclic acids. The linear or cyclic carbon-containing chain ofthe carboxylic acid or salt thereof may be substituted with asubstituent group selected from the group consisting of hydroxyl, ester,ether, aliphatic groups having from 1 to 6, alternatively 1 to 4 carbonatoms, and mixtures thereof.

Suitable carboxylic acids are those selected from the group consistingof salicylic acid, maleic acid, acetyl salicylic acid, 3 methylsalicylic acid, 4 hydroxy isophthalic acid, dihydroxyfumaric acid, 1,2,4benzene tricarboxylic acid, pentanoic acid and salts thereof, citricacid and salts thereof, and mixtures thereof. Where the carboxylic acidexists in the salt form, the cation of the salt is alternativelyselected from alkali metal, alkaline earth metal, monoethanolamine,diethanolamine or triethanolamine and mixtures thereof.

The carboxylic acid or salt thereof, when present, is present at thelevel of from 0.1% to 5%, alternatively from 0.2% to 1%, alternativelyfrom 0.25% to 0.5%, by weight of the composition.

I. Malodor Control Component

The dishwashing detergent composition comprises a malodor controlcomponent. The malodor control component may include at least onevolatile aldehyde and an acid catalyst. The malodor control component isdesigned to deliver genuine malodor neutralization and not functionmerely by covering up or masking odors. A genuine malodor neutralizationprovides a sensory and analytically measurable (e.g. gas chromatograph)malodor reduction. Thus, if the malodor control component delivers agenuine malodor neutralization, the composition will reduce malodors inthe vapor and/or liquid phase.

1. Volatile Aldehydes

The malodor control component includes a mixture of volatile aldehydesthat neutralize malodors in vapor and/or liquid phase via chemicalreactions. Such volatile aldehydes are also called reactive aldehydes(RA). Volatile aldehydes may react with amine-based odors, following thepath of Schiff-base formation. Volatiles aldehydes may also react withsulfur-based odors, forming thiol acetals, hemi thiolacetals, and thiolesters in vapor and/or liquid phase. It may be desirable for these vaporand/or liquid phase volatile aldehydes to have virtually no negativeimpact on the desired perfume character of a product. Aldehydes that arepartially volatile may be considered a volatile aldehyde as used herein.

Suitable volatile aldehydes may have a vapor pressure (VP) in the rangeof about 0.0001 torr to 100 torr, alternatively about 0.0001 torr toabout 10 torr, alternatively about 0.001 torr to about 50 torr,alternatively about 0.001 torr to about 20 torr, alternatively about0.001 torr to about 0.100 torr, alternatively about 0.001 torr to 0.06torr, alternatively about 0.001 torr to 0.03 torr, alternatively about0.005 torr to about 20 torr, alternatively about 0.01 torr to about 20torr, alternatively about 0.01 torr to about 15 torr, alternativelyabout 0.01 torr to about 10 torr, alternatively about 0.05 torr to about10 torr, measured at 25° C.

The volatile aldehydes may also have a certain boiling point (B.P.) andoctanol/water partition coefficient (P). The boiling point referred toherein is measured under normal standard pressure of 760 mmHg. Theboiling points of many volatile aldehydes, at standard 760 mm Hg aregiven in, for example, “Perfume and Flavor Chemicals (Aroma Chemicals),”written and published by Steffen Arctander, 1969.

The octanol/water partition coefficient of a volatile aldehyde is theratio between its equilibrium concentrations in octanol and in water.The partition coefficients of the volatile aldehydes used in the malodorcontrol component may be more conveniently given in the form of theirlogarithm to the base 10, logP. The logP values of many volatilealdehydes have been reported. See, e.g., the Pomona92 database,available from Daylight Chemical Information Systems, Inc. (DaylightCIS), Irvine, Calif. However, the logP values are most convenientlycalculated by the “CLOGP” program, also available from Daylight CIS.This program also lists experimental logP values when they are availablein the Pomona92 database. The “calculated logP” (ClogP) is determined bythe fragment approach of Hansch and Leo (cf., A. Leo, in ComprehensiveMedicinal Chemistry, Vol. 4, C. Hansch, P. G. Sammens, J. B. Taylor andC. A. Ramsden, Eds., p. 295, Pergamon Press, 1990). The fragmentapproach is based on the chemical structure of each volatile aldehyde,and takes into account the numbers and types of atoms, the atomconnectivity, and chemical bonding. The ClogP values, which are the mostreliable and widely used estimates for this physicochemical property,are alternatively used instead of the experimental logP values in theselection of volatile aldehydes for the malodor control component.

The ClogP values may be defined by four groups and the volatilealdehydes may be selected from one or more of these groups. The firstgroup comprises volatile aldehydes that have a B.P. of about 250° C. orless and ClogP of about 3 or less. The second group comprises volatilealdehydes that have a B.P. of 250° C. or less and ClogP of 3.0 or more.The third group comprises volatile aldehydes that have a B.P. of 250° C.or more and ClogP of 3.0 or less. The fourth group comprises volatilealdehydes that have a B.P. of 250° C. or more and ClogP of 3.0 or more.The malodor control component may comprise any combination of volatilealdehydes from one or more of the ClogP groups.

In some embodiments, the malodor control component of the presentinvention may comprise, by total weight of the malodor controlcomponent, from about 0% to about 30% of volatile aldehydes from group1, alternatively about 25%; and/or about 0% to about 10% of volatilealdehydes from group 2, alternatively about 10%; and/or from about 10%to about 30% of volatile aldehydes from group 3, alternatively about30%; and/or from about 35% to about 60% of volatile aldehydes from group4, alternatively about 35%.

Exemplary volatile aldehydes which may be used in a malodor controlcomponent include, but are not limited to, Adoxal(2,6,10-Trimethyl-9-undecenal), Bourgeonal(4-t-butylbenzenepropionaldehyde), Lilestralis 33(2-methyl-4-t-butylphenyl)propanal), Cinnamic aldehyde, cinnamaldehyde(phenyl propenal, 3-phenyl-2-propenal), Citral, Geranial, Neral(dimethyloctadienal, 3,7-dimethyl-2,6-octadien-1-al), Cyclal C(2,4-dimethyl-3-cyclohexen-1-carbaldehyde), Florhydral(3-(3-Isopropyl-phenyl)-butyraldehyde), Citronellal (3,7-dimethyl6-octenal), Cymal, cyclamen aldehyde, Cyclosal, Lime aldehyde(Alpha-methyl-p-isopropyl phenyl propyl aldehyde), Methyl NonylAcetaldehyde, aldehyde C12 MNA (2-methyl-1-undecanal),Hydroxycitronellal, citronellal hydrate (7-hydroxy-3,7-dimethyloctan-1-al), Helional(alpha-methyl-3,4-(methylenedioxy)-hydrocinnamaldehyde,hydrocinnamaldehyde (3-phenylpropanal, 3-phenylpropionaldehyde),Intreleven aldehyde (undec-10-en-1-al), Ligustral, Trivertal(2,4-dimethyl-3-cyclohexene-1-carboxaldehyde), Jasmorange, satinaldehyde(2-methyl-3-tolylproionaldehyde, 4-dimethylbenzenepropanal), Lyral(4-(4-hydroxy-4-methyl pentyl)-3-cyclohexene-1-carboxaldehyde), Melonal(2,6-Dimethyl-5-Heptenal), Methoxy Melonal(6-methoxy-2,6-dimethylheptanal), methoxycinnamaldehyde(trans-4-methoxycinnamaldehyde), Myrac aldehyde isohexenylcyclohexenyl-carboxaldehyde, trifernal ((3-methyl-4-phenyl propanal,3-phenyl butanal), lilial, P.T. Bucinal, lysmeral, benzenepropanal(4-tert-butyl-alpha-methyl-hydrocinnamaldehyde), Dupical,tricyclodecylidenebutanal (4-Tricyclo5210-2,6decylidene-8butanal),Melafleur (1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde),Methyl Octyl Acetaldehyde, aldehyde C-11 MOA (2-methyl deca-1-al),Onicidal (2,6,10-trimethyl-5,9-undecadien-1-al), Citronellyloxyacetaldehyde, Muguet aldehyde 50 (3,7-dimethyl-6-octenyl)oxyacetaldehyde), phenylacetaldehyde, Mefranal (3-methyl-5-phenylpentanal), Triplal, Vertocitral dimethyl tetrahydrobenzene aldehyde(2,4-dimethyl-3-cyclohexene-1-carboxaldehyde), 2-phenylproprionaldehyde,Hydrotropaldehyde, Canthoxal, anisylpropanal 4-methoxy-alpha-methylbenzenepropanal (2-anisylidene propanal), Cylcemone A(1,2,3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde), andPrecylcemone B (1-cyclohexene-1-carboxaldehyde).

Still other exemplary aldehydes include, but are not limited to,acetaldehyde (ethanal), pentanal, valeraldehyde, amylaldehyde, Scentenal(octahydro-5-methoxy-4,7-Methano-1H-indene-2-carboxaldehyde),propionaldehyde (propanal), Cyclocitral, beta-cyclocitral,(2,6,6-trimethyl-1-cyclohexene-1-acetaldehyde), Iso Cyclocitral(2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde), isobutyraldehyde,butyraldehyde, isovaleraldehyde (3-methyl butyraldehyde),methylbutyraldehyde (2-methyl butyraldehyde, 2-methyl butanal),Dihydrocitronellal (3,7-dimethyl octan-1-al), 2-Ethylbutyraldehyde,3-Methyl-2-butenal, 2-Methylpentanal, 2-Methyl Valeraldehyde, Hexenal(2-hexenal, trans-2-hexenal), Heptanal, Octanal, Nonanal, Decanal,Lauric aldehyde, Tridecanal, 2-Dodecanal, Methylthiobutanal,Glutaraldehyde, Pentanedial, Glutaric aldehyde, Heptenal, cis ortrans-Heptenal, Undecenal (2-, 10-), 2,4-octadienal, Nonenal (2-, 6-),Decenal (2-, 4-), 2,4-hexadienal, 2,4-Decadienal, 2,6-Nonadienal,Octenal, 2,6-dimethyl 5-heptenal, 2-isopropyl-5-methyl-2-hexenal,Trifernal, beta methyl Benzenepropanal,2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde, phenyl Butenal (2-phenyl2-butenal), 2.Methyl-3(p-isopropylphenyl)-propionaldehyde,3-(p-isopropylphenyl)-propionaldehyde, p-Tolylacetaldehyde(4-methylphenylacetaldehyde), Anisaldehyde (p-methoxybenzene aldehyde),Benzaldehyde, Vernaldehyde(1-Methyl-4-(4-methylpentyl)-3-cyclohexenecarbaldehyde), Heliotropin(piperonal) 3,4-Methylene dioxy benzaldehyde, alpha-Amylcinnamicaldehyde, 2-pentyl-3-phenylpropenoic aldehyde, Vanillin (4-methoxy3-hydroxy benzaldehyde), Ethyl vanillin (3-ethoxy4-hydroxybenzaldehyde), Hexyl Cinnamic aldehyde, Jasmonal H(alpha-n-hexyl-cinnamaldehyde), Floralozone,(para-ethyl-alpha,alpha-dimethyl Hydrocinnamaldehyde), Acalea(p-methyl-alpha-pentylcinnamaldehyde), methylcinnamaldehyde,alpha-Methylcinnamaldehyde (2-methyl 3-pheny propenal),alpha-hexylcinnamaldehyde (2-hexyl 3-phenyl propenal), Salicylaldehyde(2-hydroxy benzaldehyde), 4-ethyl benzaldehyde, Cuminaldehyde(4-isopropyl benzaldehyde), Ethoxybenzaldehyde,2,4-dimethylbenzaldehyde, Veratraldehyde (3,4-dimethoxybenz aldehyde),Syringaldehyde (3,5-dimethoxy 4-hydroxybenzaldehyde), Catechaldehyde(3,4-dihydroxybenzaldehyde), Safranal (2,6,6-trimethyl-1,3-dienemethanal), Myrtenal (pin-2-ene-1-carbaldehyde), PerillaldehydeL-4(1-methylethenyl)-1-cyclohexene-1-carboxaldehyde),2,4-Dimethyl-3-cyclohexene carboxaldehyde, 2-Methyl-2-pentenal,2-methylpentenal, pyruvaldehyde, formyl Tricyclodecan, Mandarinaldehyde, Cyclemax, Pino acetaldehyde, Corps Iris, Maceal, and Corps4322.

In one embodiment, the malodor control component includes a mixture oftwo or more volatile aldehydes selected from the group consisting of2-ethoxy Benzylaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methylFurfural, 5-methyl-thiophene-carboxaldehyde, Adoxal, p-anisaldehyde,Benzylaldehyde, Bourgenal, Cinnamic aldehyde, Cymal, Decyl aldehyde,Floral super, Florhydral, Helional, Lauric aldehyde, Ligustral, Lyral,Melonal, o-anisaldehyde, Pino acetaldehyde, P.T. Bucinal, Thiophenecarboxaldehyde, trans-4-Decenal, trans trans 2,4-Nonadienal, Undecylaldehyde, and mixtures thereof.

In some embodiments, the malodor control component includes fastreacting volatile aldehydes. “Fast reacting volatile aldehydes” refersto volatile aldehydes that either (1) reduce amine odors by 20% or morein less than 40 seconds; or (2) reduce thiol odors by 20% or more inless than 30 minutes.

In one embodiment, the malodor control component includes a mixture ofthe volatile aldehydes listed in Table 1 and referred to herein asAccord A.

TABLE 1 Accord A ClogP VP (torr) Material Wt. % CAS Number Group @25° C.Intreleven Aldehyde 5.000 112-45-8 3 0.060 Florhydral 10.000 125109-85-54 0.008 Floral Super 25.000 71077-31-1 3 0.030 Scentenal 10.00086803-90-9 2 0.010 Cymal 25.000 103-95-7 4 0.007 o-anisaldehyde 25.000135-02-4 1 0.032

In another embodiment, the malodor control component includes a mixtureof the volatile aldehydes listed in Table 2 and referred to herein asAccord B.

TABLE 2 Accord B ClogP VP (torr) Material Wt. % CAS Number Group @25° C.Intreleven Aldehyde 2.000 112-45-8 3 0.060 Florhydral 20.000 125109-85-54 0.008 Floral Super 10.000 71077-31-1 3 0.030 Scentenal 5.00086803-90-9 2 0.010 Cymal 25.000 103-95-7 4 0.007 Floralozone 10.00067634-14-4 4 0.005 Adoxal 1.000 141-13-9 4 0.007 Methyl Nonyl 1.000110-41-8 3 0.030 Acetaldehyde Melonal 1.000 106-72-9 3 0.670o-anisaldehyde 25.000 135-02-4 1 0.032

In another embodiment, the malodor control component includes a mixtureof about 71.2% volatile aldehydes, the remainder being other an esterand an alcohol perfume raw material. This mixture is listed in Table 3and referred to herein as Accord C.

TABLE 3 Accord C ClogP VP (torr) Material Wt. % CAS Number Group @25° C.Intreleven Aldehyde 2.000 112-45-8 3 0.060 Florhydral 10.000 125109-85-54 0.008 Floral Super 5.000 71077-31-1 3 0.030 Scentenal 2.000 86803-90-92 0.010 Cymal 15.000 103-95-7 4 0.007 Floralozone 12.000 67634-14-4 40.005 Adoxal 1.000 141-13-9 4 0.007 Methyl Nonyl 1.000 110-41-8 3 0.030Acetaldehyde Melonal 1.000 106-72-9 3 0.670 Flor Acetate 11.8005413-60-5 1 0.060 Frutene 7.000 17511-60-3 4 0.020 Helional 5.0001205-17-0 2 0.0005 Bourgeonal 2.000 18127-01-0 4 0.004 Linalool 10.00078-70-6 3 0.050 Benzaldehyde 0.200 100-52-7 1 1.110 o-anisaldehyde15.000 135-02-4 1 0.320

Accords A, B, or C can be formulated in with other perfume raw materialsin an amount, for example, of about 10% by weight of the malodor controlcomponent. Additionally, the individual volatile aldehydes or a variouscombination of the volatile aldehydes can be formulated into a malodorcontrol component. In certain embodiments, the volatile aldehydes may bepresent in an amount up to 100%, by weight of the malodor controlcomponent, alternatively from 1% to about 100%, alternatively from about2% to about 100%, alternatively from about 3% to about 100%,alternatively about 50% to about 100%, alternatively about 70% to about100%, alternatively about 80% to about 100%, alternatively from about 1%to about 20%, alternatively from about 1% to about 10%, alternativelyfrom about 1% to about 5%, alternatively from about 1% to about 3%,alternatively from about 2% to about 20%, alternatively from about 3% toabout 20%, alternatively from about 4% to about 20%, alternatively fromabout 5% to about 20%, by weight of the composition.

In some embodiments where volatility is not important for neutralizing amalodor, the present invention may include poly-aldehydes, for example,di-, tri-, tetra-aldehydes. Such embodiments may include laundrydetergents, additive, and the like for leave-on, through the wash, andrinse-off type of applications.

2. Acid Catalyst

The malodor control component of the present invention may include aneffective amount of an acid catalyst to neutralize sulfur-basedmalodors. It has been found that certain mild acids have an impact onaldehyde reactivity with thiols in the liquid and vapor phase. It hasbeen found that the reaction between thiol and aldehyde is a catalyticreaction that follows the mechanism of hemiacetal and acetal formationpath. When the present malodor control component contains an acidcatalyst and contacts a sulfur-based malodor, the volatile aldehydereacts with thiol. This reaction may form a thiol acetal compound, thus,neutralizing the sulfur-based odor. Without an acid catalyst, onlyhemi-thiol acetal is formed.

Suitable acid catalysts have a VP, as reported by Scifinder, in therange of about 0.001 torr to about 38 torr, measured at 25° C.,alternatively about 0.001 torr to about 14 torr, alternatively fromabout 0.001 to about 1, alternatively from about 0.001 to about 0.020,alternatively about 0.005 to about 0.020, alternatively about 0.010 toabout 0.020.

The acid catalyst may be a weak acid. A weak acid is characterized by anacid dissociation constant, K_(a), which is an equilibrium constant forthe dissociation of a weak acid; the pKa being equal to minus thedecimal logarithm of K_(a). The acid catalyst may have a pKa from about4.0 to about 6.0, alternatively from about 4.3 and 5.7, alternativelyfrom about 4.5 to about 5, alternatively from about 4.7 to about 4.9.Suitable acid catalyst include those listed in Table 4.

TABLE 4 VP (torr) @ Material 25° C. Formic Acid 36.5 Acetic Acid 13.9Trimethyl Acetic Acid 0.907 Phenol (alkaline in liquid apps yet 0.610acidic in vapor phase) Tiglic acid 0.152 Caprylic acid 0.0222 5-Methylthiophene carboxylic acid 0.019 Succinic acid 0.0165 Benzoic acid 0.014Mesitylenic acid 0.00211

Depending on the desired use of the malodor control component, one mayconsider the scent character or the affect on the scent of the malodorcontrol component when selecting an acid catalyst. In some embodimentsof the malodor control component, it may be desirable to select an acidcatalyst that provides a neutral to pleasant scent. Such acid catalystsmay have a VP of about 0.001 torr to about 0.020 torr, measured at 25°C., alternatively about 0.005 torr to about 0.020 torr, alternativelyabout 0.010 torr to about 0.020 torr. Non-limiting examples of such acidcatalyst include 5-methyl thiophene carboxaldehyde with carboxylic acidimpurity, succinic acid, or benzoic acid.

The malodor control component may include about 0.05% to about 5%,alternatively about 0.1% to about 1.0%, alternatively about 0.1% toabout 0.5%, alternatively about 0.1% to about 0.4%, alternatively about0.4% to about 1.5%, alternatively about 0.4% of an acid catalyst byweight of the malodor control component.

In an acetic acid system, the present malodor control component mayinclude about 0.4% of acetic acid (50:50 TC:DPM, 0.4% acetic acid).

TABLE 5 % Butanethiol Actual % acetic reduction Sample Formulated acidin DPM @ 30 min. 50:50 TC:DPM 0% Acetic Acid 0.00 12.00 50:50 TC:DPM0.05% Acetic Acid 0.04 14.65 50:50 TC:DPM 0.1% Acetic Acid 0.10 25.6650:50 TC:DPM 0.2% Acetic Acid 0.42 34.68 50:50 TC:DPM 0.5% Acetic Acid1.00 24.79 50:50 TC:DPM 1.0% Acetic Acid 2.00 7.26

When an acid catalyst is present with a volatile aldehyde (or RA), theacid catalyst may increase the efficacy of the volatile aldehyde onmalodors in comparison to the malodor efficacy of the volatile aldehydeon its own. For example, 1% volatile aldehyde and 1.5% benzoic acidprovides malodor removal benefit equal to or better than 5% volatilealdehyde alone.

The malodor control component may have a pH from about 3 to about 8,alternatively from about 4 to about 7, alternatively from about,alternatively from about 4 to about 6.

J. Other Optional Components:

The dishwashing detergent compositions herein can further comprise anumber of other optional ingredients suitable for use in liquiddetergent compositions such as diluents, including dipropylene glycolmethyl ether, and 3-methoxy-3-methyl-1-butanol, and mixtures thereof;dyes; pearlescent agents; opacifiers; enzymes; thickening agents;preservatives; disinfecting agents; and pH buffering means so that theliquid detergent compositions herein generally have a pH of from 3 to14, alternatively 6 to 13, alternatively 8 to 11. The pH of thecomposition can be adjusted using pH modifying ingredients known in theart.

The malodor control component may also include odor masking agents, odorblocking agents, and/or diluents. For example, the composition mayinclude a chelant, surfactant, and malodor control components comprisinga mixture of volatile aldehydes for neutralizing a malodor, perfumeionones, and a diluent. Alternatively, the malodor control component mayinclude 100% volatile aldehydes.

“Odor-masking agents” refer to known compounds (e.g. perfume rawmaterials) that mask or hide a malodorous compound. Odor-masking mayinclude a compound with a non-offensive or pleasant smell that is dosedsuch it limits the ability to sense a malodorous compound. Odor-maskingmay involve the selection of compounds which coordinate with ananticipated malodor to change the perception of the overall scentprovided by the combination of odorous compounds. “Odor blocking agents”refer to known compounds that dull the human sense of smell.

The composition may also include perfume raw materials that solelyprovide a hedonic benefit (i.e. that do not neutralize malodors yetprovide a pleasant fragrance). Suitable perfumes are disclosed in U.S.Pat. No. 6,248,135, which is incorporated in its entirety by reference.

K. Viscosity

The composition of the present invention may have viscosity from 50 to2000 centipoises (50-2000 mPa*s), alternatively from 100 to 1500centipoises (100-1500 mPa*s), alternatively from 500 to 1300 centipoises(500-1300 mPa*s) at 20^(s-1) and 20° C. Viscosity can be determined byconventional methods.

Viscosity according to the present invention is measured using an AR 550rheometer from TA instruments using a plate steel spindle at 40 mmdiameter and a gap size of 500 μm. The high shear viscosity at 20^(s-1)and low shear viscosity at 0.05^(s-1) can be obtained from a logarithmicshear rate sweep from 0.1^(s-1) to 25^(s-1) in 3 minutes time at 20° C.The preferred rheology described therein may be achieved using internalexisting structuring with detergent ingredients or by employing anexternal rheology modifier. Hence, in one embodiment of the presentinvention, the composition comprises further a rheology modifier.

II. Method of Cleaning/Treating a Dishware

The method of the present invention comprises cleaning dishware with adishwashing detergent composition comprising a cleaning agent andmalodour control component. The dishwashing operation comprises thesteps of applying said composition onto said dishware, typically indiluted or neat form and rinsing said composition from said dishware orsaid surface, or leaving the composition to dry on said surface withoutrinsing said dishware or said surface. Instead of leaving saidcomposition to dry on said surface on the air, it can also be hand-driedusing a kitchen towel. During the dishwashing operation, particularlyduring the application of the composition to the dishware and/or rinsingaway of said composition from the dishware, the hands and skin of theuser may be exposed to the composition in diluted or neat form.

By “in its neat form”, it is meant herein that the composition isapplied directly onto the surface to be treated without undergoing anydilution by the user (immediately) prior to the application. This directapplication of that said composition onto the surface to be treated canbe achieved through direct squeezing of that said composition out of thehand dishwashing liquid bottle onto the surface to be cleaned, orthrough squeezing that said composition out of the hand dishwashingliquid bottle on a pre-wetted or non pre-wetted cleaning article, suchas without intending to be limiting a sponge, a cloth or a brush, priorto cleaning the targeted surface with said cleaning article. By “dilutedform”, it is meant herein that said composition is diluted by the userwith an appropriate solvent, typically with water. By “rinsing”, it ismeant herein contacting the dishware cleaned with the process accordingto the present invention with substantial quantities of appropriatesolvent, typically water, after the step of applying the compositionherein onto said dishware. By “substantial quantities”, it is meantusually 0.1 to 20 liters.

In one embodiment of the present invention, the composition herein canbe applied in its diluted form. Soiled dishes are contacted with aneffective amount, typically from 0.5 ml to 20 ml (per 25 dishes beingtreated), alternatively from 3 ml to 10 ml, of the liquid detergentcomposition of the present invention diluted in water. The actual amountof liquid detergent composition used will be based on the judgment ofuser, and will typically depend upon factors such as the particularproduct formulation of the composition, including the concentration ofactive ingredients in the composition, the number of soiled dishes to becleaned, the degree of soiling on the dishes, and the like. Theparticular product formulation, in turn, will depend upon a number offactors, such as the intended market (i.e., U.S., Europe, Japan, etc.)for the composition product. Typical light-duty detergent compositionsare described in the examples section.

Generally, from 0.01 ml to 150 ml, alternatively from 3 ml to 40 ml,alternatively from 3 ml to 10 ml of a detergent composition of theinvention is combined with from 2000 ml to 20000 ml, more typically from5000 ml to 15000 ml of water in a sink having a volumetric capacity inthe range of from 1000 ml to 20000 ml, more typically from 5000 ml to15000 ml. The soiled dishes are immersed in the sink containing thediluted compositions then obtained, where contacting the soiled surfaceof the dish with a cloth, sponge, or similar article cleans them. Thecloth, sponge, or similar article may be immersed in the detergentcomposition and water mixture prior to being contacted with the dishsurface, and is typically contacted with the dish surface for a periodof time ranged from 1 to 10 seconds, although the actual time will varywith each application and user. The contacting of cloth, sponge, orsimilar article to the dish surface is alternatively accompanied by aconcurrent scrubbing of the dish surface.

Another method of the present invention will comprise immersing thesoiled dishes into a water bath or held under running water without anyliquid dishwashing detergent. A device for absorbing liquid dishwashingdetergent, such as a sponge, is placed directly into a separate quantityof a concentrated pre-mix of diluted liquid dishwashing detergent, for aperiod of time typically ranging from 1 to 5 seconds. The absorbingdevice, and consequently the diluted liquid dishwashing composition, isthen contacted individually to the surface of each of the soiled dishesto remove said soiling. The absorbing device is typically contacted witheach dish surface for a period of time range from 1 to 10 seconds,although the actual time of application will be dependent upon factorssuch as the degree of soiling of the dish. The step of contacting of theabsorbing device to the dish surface is alternatively accompanied byconcurrent scrubbing. Typically, said concentrated pre-mix of dilutedliquid dishwashing detergent is formed by combining 1 ml to 200 ml ofneat dishwashing detergent with 50 ml to 1500 ml of water, moretypically from 200 ml to 1000 ml of water.

III. Packaging

The detergent compositions of the present invention may be packaged inany suitable packaging for delivering the liquid detergent compositionfor use. Alternatively the package is a clear package made of glass orplastic.

Examples

The examples herein are meant to exemplify the present invention but arenot necessarily used to limit or otherwise define the scope of thepresent invention. All numerical values in the below examples are weight%, by total weight of the composition unless otherwise stated.

Ex. 1 Ex. 2 Ex. 3 Ex. 4 Ex. 5 Ex. 6 Ex. 7 Alkyl Ethoxy 22.5  25.0  25.0 27.0  20.0  22.5  22.5  Sulfate AExS* w % linear in 45   84   70   50  76   76   40   alkyl chain w % branching in 55   16   30   50   24  24   60   alkyl chain Amine oxide 8.0 6.0 7.0 5.0 5.0 8.0 7.0 NonionicC9-11 EO8 7.0 — — 3.0 5.0 — 4.0 (15% branching) Ethylan 1008 — — 3.0 — —7.0 — (100% branching) Lutensol TO7 — 7.0 — — 5.0 — 3.0 (100% branching)GLDA¹ 1.0 — — — 1.0 0.5 0.8 DTPMP² — 1.0 — — 0.5 — 0.4 DTPA³ — — 1.0 — —— — MGDA⁴ — — — 1.0 — 0.5 — Sodium Citrate — — 1.0 — 0.5 0.8 — Solvent:ethanol, 2.5 7.0 4.0 3.0 2.0 3.0 2.5 isopropylalcohol, . . .Polypropylene glycol 1.0 1.5 0.5 1.0 — 2.0 1.0 MW2000 Sodium Chloride0.5 0.8 1.0 1.0 0.5 0.5 0.5 Average branching 35.8  28.9  30.0  39.8 30.1  33 46.8  weight % in total surfactant mixture Total Surfactant/5.3 5.4 11.6 11.7 3.5 5.4 5.2 Nonionic weight ratio Ex. 8 Ex. 9 Ex. 10Ex. 11 Alkyl Ethoxy Sulfate AExS* 13   16   17   15   w % linear inalkyl chain 70   60   84   45   w % branching in alkyl chain 30   40  16   55   Amine oxide 4.5 5.5 6.0 5.0 Nonionic C9-11 EO8 (15% branching)— 2.0 — 5   Ethylan 1008 (100% branching) — 2.0 — — Lutensol TO7 (100%branching) 4   — 5   — GLDA¹ 0.7 0.4 0.7 0.7 DTPMP² — 0.3 — — SodiumCitrate — — 0.2 — Solvent: ethanol, isopropylalcohol, . . . 2.0 2.0 2.01.0 Polypropylene glycol MW 2000 0.5 0.3 0.5 0.4 Salt: Sodium Chloride0.5 0.8 0.4 0.5 Average branching weight % in total 17.3  14.9  12.4 36.0  surfactant mixture Total surfactant/Nonionic weight ratio 5.4 6.45.6 5.0 Ex. Ex. Ex. Ex. Ex. 12 13 14 15 16 Linear Alkylbenzene Sulfonate21.0  21.0  12.0  13.0  — Alkyl Ethoxy Sulfate AExS* — — 14.0  5.0 17.0 w % linear in alkyl chain 76   84   60   w % branching in alkyl chain24   16   40   C12-14 alpha olefin sulfonate — — — — 6.0 Coco amidopropyl Amine Oxide — — — 1.0 5.0 alkylpolyglucoside — 2.0 — — — NonionicC9-11 EO8 (15% branching) — — 8.0 — 3.0 Lutensol TO7 (100% branching)5.0 4.0 — 8.0 — GLDA¹ 0.5 — — — — DTPMP² — 0.8 — — — DTPA³ — — 0.5 0.8 —MGDA⁴ — — — — 1.0 Average branching weight % in total 19.2  14.8  13.4 32.6  23.4  surfactant mixture Total surfactant/Nonionic 5.2 4.5 4.2 3.410.3  weight ratio Ex. Ex. Ex. Ex. Ex. 17 18 19 20 21 Alkyl EthoxySulfate AExS* 17.0  12.0  24.5  18.0  29.0  w % linear in alkyl chain40   76   84   70   70   w % branching in alkyl chain 60   24   16  30   30   C12-14 alpha olefin sulfonate — — 1.0 — — Paraffin Sulfonate(C15) 9.0 1.0 1.0 — — Coco amido propyl amine oxide — 6.0 — — 1.0 Cocoamido propyl Betaine — — — 5.0 — Alkylpolyglucoside — 3.0 — — — NonionicC9-11 EO8 (15% branching) 8.0 — — 3.0 — Lutensol TO7 (100% branching) —2.0 2.5 — 4.0 GLDA¹ 0.5 — — — — DTPMP² — 0.8 — — — DTPA³ — — 0.5 0.8 —MGDA⁴ — — — — 1.0 Polypropylene glycol MW2000 1.0 1.0 — 0.5 0.5 Averagebranching weight % in total 33.5  20.3  22.1  22.5  37.4  surfactantmixture Total surfactant/Nonionic 4.2 4.8 11.6  8.7 8.5 weight ratioBalance of Minors (**), Malodor Control Component, and water up to 100%*Alkyl chain between C10 and C14, alternatively between C12-13 and x =between 0 and 4, alternatively between 0.5 and 2 (**) Minors: dyes,opacifiers, perfumes, preservatives, hydrotropes, processing aids,salts, stabilizers . . . ¹Glutamic acid ²Diethylenetriamine pentamethylphosphonic acid ³Diethylenetriamine pentaacetic acid ⁴Methylglycinediacetic acid

Analytical Test—Effect of Volatile Aldehydes on Amine-Based andSulfur-Based Malodors

Malodor standards are prepared by pipeting 1 mL of butylamine(amine-based malodor) and butanethiol (sulfur-based malodor) into a 1.2liter gas sampling bag. The bag is then filled to volume with nitrogenand allowed to sit for at least 12 hours to equilibrate.

A 1 μL sample of each volatile aldehyde listed in Table 6 and of eachAccord (A, B, and C) listed in Tables 1 to 3 is pipeted into individual10 mL silanized headspace vials. The vials are sealed and allowed toequilibrate for at least 12 hours. Repeat 4 times for each sample (2 forbutylamine analysis and 2 for butanethiol analysis).

After the equilibration period, 1.5 mL of the target malodor standard isinjected into each 10 mL vial. For thiol analysis, the vials containinga sample+malodor standard are held at room temperature for 30 minutes.Then, a 1 mL headspace syringe is then used to inject 250 μL of eachsample/malodor into a GC/MS split/splitless inlet. For amine analysis, a1 mL headspace syringe is used to inject 500 μL of each sample/malodorimmediately into the GC/MS split/splitless inlet. A GC pillow is usedfor the amine analysis to shorten the run times.

Samples are then analyzed using a GC/MS with a DB-5, 20 m, 1 μm filmthickness column with an MPS-2 autosampler equipment with staticheadspace function. Data is analyzed by ion extraction on each total ioncurrent (56 for thiol and 30 for amine) and the area is used tocalculate the percent reduction from the malodor standard for eachsample.

Table 6 shows the effect of certain volatile aldehydes on neutralizingamine-based and sulfur based malodors at 40 seconds and 30 minutes,respectively.

TABLE 6 At least 20% At least 20% butylamine butanethiol reductionreduction Perfume Raw Material (R—CHO) at 40 secs.? at 30 mins.? 2,4,5Trimethoxy Benzaldehyde No No 2,4,6-Trimethoxy-benzylaldehyde No No2-ethoxy benzylaldehyde Yes Yes 2-isopropyl-5-methyl-2-hexenal Yes Yes2-methyl-3-(2-furyl)-propenal No No 3,4,5 Trimethoxy Benzaldehyde No No3,4-Trimethoxy-benzylaldehyde No No 4-tertbutyl benzylaldehyde Yes No5-methyl furfural Yes Yes 5-methyl-thiophene-carboxaldehyde No YesAdoxal Yes No Amyl cinnamic aldehyde No No Benzylaldehyde Yes NoBourgenal No Yes Cinnamic aldehyde Yes Yes Citronelyl Oxyacetaldehyde NoNo Cymal Yes No Decyl aldehyde Yes No Floral Super Yes Yes FlorhydralYes Yes Floralozone No No Helional Yes No Hydroxycitronellal No NoLauric aldehyde Yes No Ligustral Yes No Lyral Yes No Melonal Yes NoMethyl nonyl acetaldehyde No No o-anisaldehyde Yes Yes p-anisaldehydeYes No Pino acetaldehyde Yes Yes P.T. Bucinal Yes No ThiopheneCarboxaldehyde Yes No Trans-4-decenal Yes Yes Trans Trans 2,4-NonadienalYes No Undecyl aldehyde Yes No

Table 7 shows the percent reduction of butylamine and butaniethiol at 40seconds and 30 minutes, respectively, for Accords A, B, and C.

TABLE 7 % reduction of butylamine at % reduction of butanethiol atAccord 40 secs. 30 mins. Accord A 76.58 25.22 Accord B 51.54 35.38Accord C 65.34 24.98

Analytical Test—Effect of Acid Catalysts on Sulfur-Based Malodors

The above analytical test is repeated using samples containing an acidcatalyst to test their effect on sulfur-based malodors. Specifically, a1 μL aliquot of each of the following controls and acid catalyst samplesare pipeted into individual 10 mL silanized headspace vials induplicate: thiophene carboxyaldehyde as a control; a 50/50 mixture ofthiophene carboxaldehyde and each of the following acid catalysts at0.04%, 0.10%, 0.43% in DPM, 1.02% in DPM, and 2.04% in DPM: phenol,mesitylenic acid, caprylic acid, succinic acid, pivalic acid, tiglicacid, and benzoic acid.

FIG. 1 demonstrates that low vapor pressure acid catalysts provide up to3 times better reduction of sulfur-based malodors in comparison to thecontrol.

Analytical Test—Effect of Volatile Aldehydes and Acid Catalyst onAmine-Based and Sulfur-Based malodors

The above analytical test is repeated using sample formulationscontaining volatile aldehydes (or RA) and an acid catalyst, as outlinedin Tables 8 and 9.

Tables 8 and 9 show that a perfume mixture having as little as 1%volatile aldehyde along with 1.5% acid catalyst performs better atreducing butylamine and butanethiol than the same perfume mixture having5% volatile aldehyde.

TABLE 8 % butylamine % butanethiol reduction at reduction at Formulation40 secs. 30 mins. Perfume Mixture w/ 5% RA 34.21 — 2.40 — (Control)Perfume Mixture w/ 1% RA and 41.63 +7.42 11.95 +9.55 w/ 1.5% BenzoicAcid Perfume Mixture w/ 3% RA and 36.19 +1.98 13.56 +11.16  w/ 1.5%Benzoic Acid Perfume A Mixture w/ 5% RA and 41.26 +7.05 9.56 +5.02 w/1.5% Benzoic Acid

TABLE 9 % butylamine % butanethiol Reduction at reduction at Formulation40 secs. 30 mins. Perfume mixture w/ 5% RA 4.94 — 10.52 — (Control)Perfume mixture w/ 1% RA and 11.61  +6.67 18.82 +8.30 w/ 1.5% BenzoicAcid Perfume mixture w/ 3% RA and 26.89 +21.95 14.85 +4.33 w/ 1.5%Benzoic Acid Perfume mixture w/ 5% RA and 20.27 +15.33 16.84 +6.32 w/1.5% Benzoic Acid

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm.”

Every document cited herein, including any cross referenced or relatedpatent or application, is hereby incorporated herein by reference in itsentirety unless expressly excluded or otherwise limited. The citation ofany document is not an admission that it is prior art with respect toany invention disclosed or claimed herein or that it alone, or in anycombination with any other reference or references, teaches, suggests,or discloses any such invention. Further, to the extent that any meaningor definition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is, therefore,intended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed:
 1. A dishwashing detergent composition comprising: (a)from about 0.1% to about 20% by weight of the total composition of achelant; (b) from about 5% to about 80% by weight of the totalcomposition of a surfactant selected from the group consisting ofanionic, nonionic, cationic, amphoteric, zwitterionic, semi-polarnonionic surfactants and mixtures thereof; and (c) a malodor controlcomponent comprising an effective amount of two or more volatilealdehydes for neutralizing a malodor, wherein said two or more volatilealdehydes are selected from the group consisting of 2-ethoxybenzylaldehyde, 2-isopropyl-5-methyl-2-hexenal, 5-methyl furfural,5-methyl-thiophene-carboxaldehyde, adoxal, p-anisaldehyde,benzylaldehyde, bourgenal, cinnamic aldehyde, cymal, decyl aldehyde,floral super, florhydral, helional, lauric aldehyde, ligustral, lyral,melonal, o-anisaldehyde, pino acetaldehyde, P.T. bucinal, thiophenecarboxaldehyde, trans-4-decenal, trans trans 2,4-nonadienal, undecylaldehyde, and mixtures thereof.
 2. The composition of claim 1 whereinsaid two or more volatile aldehydes are selected from the groupconsisting of 2-ethoxy benzylaldehyde, 2-isopropyl-5-methyl-2-hexenal,5-methyl furfural, cinnamic aldehyde, floral super, florhydral,o-anisaldehyde, pino acetaldehyde, trans-4-decenal, and mixturesthereof.
 3. The composition of claim 1 wherein said two or more volatilealdehydes comprise flor super and o-anisaldehyde.
 4. The composition ofclaim 1 wherein said two or more volatile aldehydes have a VP from about0.001 torr to about 0.100 torr.
 5. The composition of claim 1 whereinsaid two or more volatile aldehydes comprise about 25% of quad Ivolatile aldehydes, by weight of said malodor control component.
 6. Thecomposition of claim 1 wherein said mixture of two or more volatilealdehydes comprise about 10% of quad II volatile aldehydes, by weight ofsaid malodor control component.
 7. The composition of claim 1 whereinsaid mixture of two or more volatile aldehydes comprise from about 10%to about 30% of quad III volatile aldehydes, by weight of said malodorcontrol component.
 8. The composition of claim 1 wherein said mixture oftwo or more volatile aldehydes comprise from about 35% to about 60% ofquad IV volatile aldehydes, by weight of said malodor control component.9. The composition of claim 1 wherein said two or more volatilealdehydes is selected from the group consisting of: Accord A, Accord B,Accord C, and mixtures thereof.
 10. The composition of claim 1 whereinsaid two or more volatile aldehydes comprise about 1% to about 10% ofAccord A, by weight of said malodor control component.
 11. Thecomposition of claim 1 wherein said composition has a pH of about 4 toabout 6.5.
 12. The composition of claim 1 wherein said two or morevolatile aldehydes comprise three or more volatile aldehydes having a VPof about 0.001 torr to about 0.100 torr.
 13. The composition of claim 1wherein said two or more volatile aldehydes are present in an amountfrom about 0.015% to about 1%, by weight of said dishwashing detergentcomposition.
 14. The composition of claim 1 wherein said malodor controlcomponent further comprises an acid catalyst having a vapor pressure ofabout 0.01 to about 13 at 25° C.
 15. The composition of claim 1 whereinsaid surfactant is present in an amount from about 10% to about 60% byweight of said composition.
 16. The composition of claim 1 wherein saidsurfactant is present in an amount from about 12% to about 45% by weightof said composition.
 17. The composition of claim 1 wherein saidsurfactant is selected from the group consisting of amine oxidesurfactants, betaines surfactants, and mixture thereof.
 18. Thecomposition of claim 17 wherein said surfactant is a coco dimethyl amineoxide.
 19. The composition of claim 1 wherein the average alkyl chainbranching is at least about 40% by weight of the total surfactants. 20.The composition of claim 1 wherein the average alkyl chain branching isprovided by a branched nonionic surfactant selected from the groupconsisting of Guerbet alcohol ethoxylates, Guerbet alcohol alkoxylatedEO/PO nonionics, oxo branched nonionic surfactants; derivatives from theisotridecyl alcohol and modified with ethyleneoxyde, and mixturesthereof.
 21. The composition of claim 1 further comprising a nonionicsurfactant present in an amount from about 3% to about 20%, by weight ofsaid composition.
 22. The composition of claim 21 wherein the weightratio of total surfactant to nonionic surfactant is from about 2 toabout
 6. 23. The composition of claim 1 wherein said chelant is presentin an amount from about 0.1% to about 20% by weight of said composition.24. The composition of claim 1 wherein said chelant is selected from thegroup consisting of Glutamic acid, Diethylenetriamine pentamethylphosphonic acid; Diethylenetriamine pentaacetic acid, Methylglycinediacetic acid and mixtures thereof.
 25. The composition of claim1 wherein said composition further comprises uncomplexed cyclodextrin.26. The composition of claim 1 wherein said composition furthercomprises a water-soluble metallic salt selected from the groupconsisting of: zinc salts, copper salts, and mixtures thereof.
 27. Adishwashing detergent composition comprising: (a) a chelant; (b) asurfactant selected from the group consisting of anionic, nonionic,cationic, amphoteric, zwitterionic, semi-polar nonionic surfactants, andmixtures thereof; and (c) a malodor control component comprising: (i) atleast one volatile aldehyde; and (ii) an acid catalyst having a vaporpressure of about 0.01 to about 13 at 25° C.; and (b) about 1% to about5%, by weight of said composition, of a low molecular weight monohydricalcohol.
 28. The composition of claim 27 wherein said at least onevolatile aldehyde has a VP of about 0.001 to about 50 torr.
 29. Thecomposition of claim 27 wherein said at least one volatile aldehyde hasa VP of about 0.001 torr to about 15 torr.
 30. The composition of claim27 wherein said at least one volatile aldehyde is selected from thegroup consisting of 2-ethoxy benzylaldehyde,2-isopropyl-5-methyl-2-hexenal, 5-methyl furfural,5-methyl-thiophene-carboxaldehyde, adoxal, p-anisaldehyde,benzylaldehyde, bourgenal, cinnamic aldehyde, cymal, decyl aldehyde,floral super, florhydral, helional, lauric aldehyde, ligustral, lyral,melonal, o-anisaldehyde, pino acetaldehyde, P.T. bucinal, thiophenecarboxaldehyde, trans-4-decenal, trans trans 2,4-nonadienal, undecylaldehyde, and mixtures thereof.
 31. The composition of claim 27 whereinsaid at least one volatile aldehyde is selected from the groupconsisting of flor super, o-anisaldehyde, and mixtures thereof.
 32. Thecomposition of claim 27 wherein said at least one volatile aldehyde ispresent in an amount from about 1% to about 10%, by weight of saidmalodor control component.
 33. The composition of claim 27 wherein saidat least one volatile aldehyde is present in an amount from about 0.015%to about 1%, by weight of said dishwashing detergent composition. 34.The composition of claim 27 wherein said at least one volatile aldehydecomprises a mixture of volatile aldehydes selected from the groupconsisting of Accord A, Accord B, Accord C, and mixtures thereof. 35.The composition of claim 27 wherein said at least one volatile aldehydeis present in an amount from about 1% to about 5%, by weight of saidmalodor control component, and said acid catalyst is present in anamount of about 0.4% to about 1.5%, by weight of said malodor controlcomponent.
 36. The composition of claim 27 wherein said acid catalyst ispresent in an amount from about 0.1% to about 0.4%, by weight of saidmalodor control composition.
 37. The composition of claim 27 whereinsaid acid catalyst has a vapor pressure of about 0.01 to about 2 torr at25° C.
 38. The composition of claim 27 wherein said acid catalyst is acarboxylic acid.
 39. The composition of claim 27 wherein said acidcatalyst is 5-methyl thiophene carboxylic acid.
 40. A method of cleaninga dishware comprising the steps of: (a) applying a composition accordingto claim 1 on said dishware; and (b) rinsing said composition off ofsaid dishware.